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Metathesis

“Metathesis is one of the most spectacular recent improvements in synthetic strategies for organic synthesis and polymer science.” - Didier Astruc, New Journal of Chemistry Articles
Functional Polymers Print E-mail

 

Various metathesis processes produce a wide variety of functional oligomers and polymers. An excellent example of this is a dihydroxy telechelic polymer. These telechelic materials have several important and growing industrial applications including the production of multi-block polymers such as styrene-butadiene-styrene (Kraton) and thermoplastic polyurethanes. High quality telechelic materials are, however, notoriously difficult or impossible to prepare by other methods. The figure below shows an example of telechelic synthesis.

 

 

Hillmyer, M. A.; Grubbs, R. H. Macromolecules 1993, 26, 872
Hillmyer, M. A.; Grubbs, R. H. Macromolecules 1995, 28, 8662